Data availability
The data that support the findings of this study can be found in the paper and the Supplementary Information and are available from the corresponding authors upon request.
Code availability
The DFT calculations were performed using VASP v.6.3.2, which is commercially available at https://www.vasp.at/. The custom scripts and VASP input files generated during the current study are available from the corresponding authors upon request.
References
Liu, Y. et al. Promises and prospects of two-dimensional transistors. Nature 591, 43–53 (2021).
Article ADS CAS PubMed Google Scholar
Rhodes, D., Chae, S. H., Ribeiro-Palau, R. & Hone, J. Disorder in van der Waals heterostructures of 2D materials. Nat. Mater. 18, 541–549 (2019).
Article CAS PubMed Google Scholar
Das, S. et al. Transistors based on two-dimensional materials for future integrated circuits. Nat. Electron. 4, 786–799 (2021).
Article ADS CAS Google Scholar
Fu, J.-H., Chen, D.-C., Wu, Y.-J. & Tung, V. Constructing two-dimensional, ordered networks of carbon–carbon bonds with precision. Precis. Chem. 3, 3–9 (2025).
Article CAS PubMed Google Scholar
Choi, S. H. et al. Large-scale synthesis of graphene and other 2D materials towards industrialization. Nat. Commun. 13, 1484 (2022).
Article ADS CAS PubMed PubMed Central Google Scholar
Wang, Y. et al. P-type electrical contacts for 2D transition-metal dichalcogenides. Nature 610, 61–66 (2022).
Article ADS PubMed Google Scholar
Kim, K. S. et al. The future of two-dimensional semiconductors beyond Moore’s law. Nat. Nanotechnol. 19, 895–906 (2024).
Article ADS CAS PubMed Google Scholar
Kim, K. S. et al. Growth-based monolithic 3D integration of single-crystal 2D semiconductors. Nature 636, 615–621 (2024).
Article ADS CAS PubMed Google Scholar
Kim, K. S. et al. Non-epitaxial single-crystal 2D material growth by geometric confinement. Nature 614, 88–94 (2023).
Article ADS CAS PubMed Google Scholar
Zhao, B. et al. Gate-driven band modulation hyperdoping for high-performance p-type 2D semiconductor transistors. Science 388, 1183–1188 (2025).
Article ADS CAS PubMed Google Scholar
Wang, H. et al. Seeded growth of single-crystal black phosphorus nanoribbons. Nat. Mater. 23, 470–478 (2024).
Article CAS PubMed Google Scholar
Ci, L. et al. Atomic layers of hybridized boron nitride and graphene domains. Nat. Mater. 9, 430–435 (2010).
Article CAS PubMed Google Scholar
Xiong, Y. et al. Vapour–liquid–solid–solid growth of two-dimensional non-layered β-Bi2O3 crystals with high hole mobility. Nat. Mater. 24, 688–697 (2025).
Article CAS PubMed Google Scholar
Liu, A. et al. Selenium-alloyed tellurium oxide for amorphous p-channel transistors. Nature 629, 798–802 (2024).
Article ADS CAS PubMed PubMed Central Google Scholar
Ghosh, S. et al. A complementary two-dimensional material-based one instruction set computer. Nature 642, 327–335 (2025).
Article ADS CAS PubMed Google Scholar
Chen, T.-A. et al. Wafer-scale single-crystal hexagonal boron nitride monolayers on Cu (111). Nature 579, 219–223 (2020).
Article ADS CAS PubMed Google Scholar
Ma, K. Y. et al. Epitaxial single-crystal hexagonal boron nitride multilayers on Ni (111). Nature 606, 88–93 (2022).
Article ADS CAS PubMed Google Scholar
Fukamachi, S. et al. Large-area synthesis and transfer of multilayer hexagonal boron nitride for enhanced graphene device arrays. Nat. Electron. 6, 126–136 (2023).
Article CAS Google Scholar
Kong, W. et al. Path towards graphene commercialization from lab to market. Nat. Nanotechnol. 14, 927–938 (2019).
Article ADS CAS PubMed Google Scholar
Novoselov, K. S. et al. Electric field effect in atomically thin carbon films. Science 306, 666–669 (2004).
Article ADS CAS PubMed Google Scholar
Shi, Z., Kutana, A. & Yakobson, B. I. How much n-doping can graphene sustain? J. Phys. Chem. Lett. 6, 106–112 (2015).
Article CAS PubMed Google Scholar
Kaner, R. B., Kouvetakis, J., Warble, C. E., Sattler, M. L. & Bartlett, N. Boron-carbon-nitrogen materials of graphite-like structure. Mater. Res. Bull. 22, 399–404 (1987).
Article ADS CAS Google Scholar
Mendelson, N. et al. Identifying carbon as the source of visible single-photon emission from hexagonal boron nitride. Nat. Mater. 20, 321–328 (2021).
Article CAS PubMed Google Scholar
Cheng, T., Bets, K. V. & Yakobson, B. I. Synthesis landscapes for ammonia borane chemical vapor deposition of h-BN and BNNT: unraveling reactions and intermediates from first-principles. J. Am. Chem. Soc. 146, 9318–9325 (2024).
Article ADS CAS PubMed Google Scholar
Weng-Sieh, Z. et al. Synthesis of BxCyNz nanotubules. Phys. Rev. B 51, 11229(R)–11232(R) (1995).
Article ADS Google Scholar
Gao, J., Yip, J., Zhao, J., Yakobson, B. I. & Ding, F. Graphene nucleation on transition metal surface: structure transformation and role of the metal step edge. J. Am. Chem. Soc. 133, 5009–5015 (2011).
Article ADS CAS PubMed Google Scholar
Kang, K. et al. High-mobility three-atom-thick semiconducting films with wafer-scale homogeneity. Nature 520, 656–660 (2015).
Article ADS CAS PubMed Google Scholar
Fu, J.-H. et al. Oriented lateral growth of two-dimensional materials on c-plane sapphire. Nat. Nanotechnol. 18, 1289–1294 (2023).
Article ADS CAS PubMed Google Scholar
Stephan, O. et al. Doping graphitic and carbon nanotube structures with boron and nitrogen. Science 266, 1683–1685 (1994).
Article ADS CAS PubMed Google Scholar
Kouvetakis, J. et al. Novel aspects of graphite intercalation by fluorine and fluorides and new B/C, C/N and B/C/N materials based on the graphite network. Synth. Met. 34, 1–7 (1989).
Article CAS Google Scholar
Pimenta, M. A. et al. Studying disorder in graphite-based systems by Raman spectroscopy. Phys. Chem. Chem. Phys. 9, 1276–1290 (2007).
Article CAS PubMed Google Scholar
Chen, P.-J. et al. Visualizing local superconductivity of NbTiN nanowires to probe inhomogeneity in single-photon detectors. ACS Appl. Opt. Mater. 2, 68–75 (2024).
Article CAS Google Scholar
Chou, S.-A. et al. Large-scale alkali-assisted growth of monolayer and bilayer WSe2 with a low defect density. Nat. Commun. 16, 2777 (2025).
Article ADS CAS PubMed PubMed Central Google Scholar
Kwon, G. et al. Interaction- and defect-free van der Waals contacts between metals and two-dimensional semiconductors. Nat. Electron. 5, 241–247 (2022).
Article CAS Google Scholar
Zhu, H. et al. Step engineering for nucleation and domain orientation control in WSe2 epitaxy on c-plane sapphire. Nat. Nanotechnol. 18, 1295–1302 (2023).
Article ADS CAS PubMed Google Scholar
Zhang, B. Y. et al. Hexagonal metal oxide monolayers derived from the metal–gas interface. Nat. Mater. 20, 1073–1078 (2021).
Article CAS PubMed Google Scholar
Wu, R. et al. Bilayer tungsten diselenide transistors with on-state currents exceeding 1.5 milliamperes per micrometre. Nat. Electron. 5, 497–504 (2022).
Article CAS Google Scholar
Download references
Acknowledgements
V.T. acknowledges the equipment support from TuoTuo Technology (lithography), Enli-Technology (Probe station), Kate Chuang (illustration design) and Kao Duen Technology. We thank C.-Y. Tien, A. Yamada, K. Takanabe and C.-C. Chang for their discussions.
Funding
C.-C.T., J.-H.F. and V.T. are indebted to the financial support from the Japan Society for the Promotion of Science (JSPS, 26H02218, 23H00253, 24K21233 and 25KF0196), JST ASPIRE (grant no. JPMJAP2531), and JST CREST (grant no. JPMJCR24A3). W.-C.C. and F.-Z.C. acknowledge the support from NSTC 113-2119-M-492-001-MBK and NSTC 114-2622-E-492-001. J.-C.K. and C.-W.P. thank the support from the Academia Sinica Investigator Award (grant no. AS-IA-112-M05) and the National Science and Technology Council, Taiwan (111-2112-M-001-085-MY3). We thank the National Center for High-performance Computing (NCHC) for providing computational and storage resources. C.-H.H. and Y.-C.C. acknowledge the support from the Partnership Program for the Connection to the Top Labs in the World—Dragon Gate Program (113-2926-I-002-511-G) and 113-2628-E-002-021-MY4. J.-C.K. and Y.-C.L. acknowledge the support from NSTC (grant no. 113-2221-E-A49-012-MY3). M.-C.W. and V.T. express their gratitude for the financial support provided by the Chang Gung University (URRPD2Q0041).
Ethics declarations
Competing interests
The authors declare no competing interests.
Peer review
Peer review information
Nature thanks Sang-Hoon Bae, Yong-Young Noh and the other, anonymous, reviewer(s) for their contribution to the peer review of this work. Peer reviewer reports are available.
Additional information
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary information
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
Reprints and permissions
About this article
Cite this article
Tseng, CC., Huang, CH., Kao, JC. et al. Wafer-scale epitaxy growth of high-mobility p-type boron carbon nitride. Nature (2026). https://doi.org/10.1038/s41586-026-11047-9
Download citation
Received:
Accepted:
Published:
Version of record:
DOI: https://doi.org/10.1038/s41586-026-11047-9